231609-28-2Relevant articles and documents
Cobalt-complexed propargyl cations: Generation under neutral conditions and spontaneous, high-temperature conversion to propargyl Radicals
Melikyan, Gagik G.,Sepanian, Ruth,Spencer, Ryan,Rowe, Aaron,Toure, Pogban
, p. 5541 - 5549 (2010/01/06)
A novel method for the generation of Co2(CO)6- complexed propargyl cations under neutral conditions is developed. The optimized experimental protocol involves treatment of the respective Co 2(CO)6-complexed prop
Cobalt-templated radical processes: Inter- and intramolecular coupling of propargyl radicals
Melikyan, Gagik G.,Deravakian, Asatour,Myer, Steven,Yadegar, Sarkhadoun,Hardcastle, Kenneth I.,Ciurash, Joana,Toure, Pogban
, p. 68 - 75 (2007/10/03)
A novel method for radical C-C bond formation in the α-position to Co2(CO)6-clusters has been elaborated. The two-dimensional exploration of the process resulted in the discovery of structurally diverse O- and S-containing organic molecules capable of acting as efficient mediators in reductive coupling reactions, and in the elaboration of the preparative synthesis of 3,4-disubstituted 1,5-alkadiynes and carbocycles with eight- and nine-membered rings.