231616-32-3

Upstream product

• 130531-38-3 2-(trimethylsilyl)ethyl-6-O-(tert-butyldimethylsilyl)-β-D-galactopyranoside 
• 117252-95-6 2-(trimethylsilyl)ethyl β-D-galactopyranoside 

Downstream Products

• 231616-41-4 2-(trimethylsilyl)ethyl 2,3,4,6-tetra-O-benzoyl-β-D-galactopyranosyl(1->6)-2,3,4-tri-O-benzoyl-β-D-galactopyranoside 
• 250123-36-5 2-(trimethylsilyl)ethyl 4,6-O-benzylidene-2,3-di-O-benzoyl-β-D-galacto-pyranosyl-(1->6)-2,3,4-tri-O-benzoyl-β-D-galactopyranoside 
• 493012-75-2 C₆₇H₆₅O₂₀PSi 
• 1063698-02-1 2-(trimethylsilyl)ethyl 2,3,4-tri-O-benzoyl-6-O-chloroacetyl-β-D-galactopyranosyl-(1->6)-2,3,4-tri-O-benzoyl-β-D-galactopyranoside 
• 231616-50-5 2-(trimethylsilyl)ethyl 2,3,4-tri-O-benzyl-α-L-fucopyranosyl-(1->3)-2,4,6-tri-O-acetyl-β-D-galactopyranosyl-(1->6)-2,3,4-tri-O-benzoyl-β-D-galactopyranoside 
• 231616-51-6 2-(trimethylsilyl)ethyl 2,3,4-tri-O-acetyl-α-L-fucopyranosyl-(1->3)-2,4,6-tri-O-acetyl-β-D-galactopyranosyl-(1->6)-2,3,4-tri-O-benzoyl-β-D-galactopyranoside 
• 231616-52-7 2,3,4-tri-O-acetyl-α-L-fucopyranosyl-(1->3)-2,4,6-tri-O-acetyl-β-D-galactopyranosyl-(1->6)-2,3,4-tri-O-benzoyl-α-D-galactopyranosyl trichloroacetimidate 
• 231616-43-6 2,3,4,6-tetra-O-benzoyl-β-D-galactopyranosyl-(1->6)-2,3,4-tri-O-benzoyl-α-D-galactopyranosyl trichloroacetimidate 
• 231616-47-0 2-(trimethylsilyl)ethyl 2,4-di-O-acetyl-3-O-benzyl-β-D-galactopyranosyl-(1->6)-2,3,4-tri-O-benzoyl-β-D-galactopyranoside 
• 231616-48-1 2-(trimethylsilyl)ethyl 2,4,6-tri-O-acetyl-β-D-galactopyranosyl-(1->6)-2,3,4-tri-O-benzoyl-β-D-galactopyranoside 
• 493013-07-3 C₆₈H₆₇O₂₀PSi 

Relevant academic research and scientific papers

Synthetic studies on glycosphingolipids from the parasite Echinococcus multilocularis

Novel neutral glycosphingolipids isolated from the metacestodes of Echinococcus multilocularis by Persat, may be expected to be involved in host-parasite interactions. We have synthesized these glycosphingolipid analogues containing 2-branched fatty alkyl residues in place of ceramide. The glycosylation of galactosyl donors 4 and 5 with each of the acceptors 2 and 11 in the presence of N-iodosuccinimide (NIS)/TfOH, and the glycosylation of fucosyl donor 13 with acceptors 12 and 20 in the presence of dimethyl(methylthio)sulfonium triflate (DMTST) gave the desired oligosaccharide derivatives at good yield. The fully per-O-acylated 2-(trimethylsilyl)ethyl glycosides 6, 15, 21, and 26 were converted to glycosylimidates 7, 16, 22, and 27, which were condensed with 2-(tetradecyl)hexadecanol and subsequently deacylated give four target glycosphingolipid analogues. Copyright (C) 1999 Elsevier Science Ltd.