231620-10-3Relevant academic research and scientific papers
Enantioselective reduction of α,β-unsaturated acylsilanes by chiral lithium amides
Takeda, Kei,Ohnishi, Yuji,Koizumi, Toru
, p. 237 - 239 (1999)
(equation presented) Reaction of β-substituted acryloylsilanes I with lithium amides II affords α-silyl allylic alcohols III in high enantiomeric excess (>99percent) via formal hydride transfer from the chiral lithium amide.
