23183-97-3Relevant academic research and scientific papers
A new catalytic route for the activation of sp-hybridized carbon-hydrogen bonds
Marciniec, Bogdan,Dudziec, Beata,Kownacki, Ireneusz
, p. 8180 - 8184 (2008/02/08)
(Chemical Equation Presented) Vinyl-substituted silicon compounds react selectively with terminal alkynes in the presence of complexes containing [Ru]-H and [Ru]-Si bonds to form functionalized silylethynes (see picture). This reaction opens up a new catalytic route for the preparation of a class of potent organosilicon reagents for organic synthesis.
