23228-89-9Relevant articles and documents
PREPARATION OF SELECTED FLUOROOLEFINS
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Page 4, (2008/06/13)
A process is disclosed for producing (CF3)2C=CH2, CF3CH=CF2, CF2=C(CF3)OCF2CHF2 and C6H5C(CF3)=CF2. The process involves contacting the corresponding fluorocarbon starting material selected from (CF3)2CFCH2F, (CF3)2CHF, (CF3)2CFOCF2CHF2 and C6H5CF(CF3)2, in the vapor phase, with a defluorination reagent selected from carbon, copper, iron, nickel and zinc at an elevated temperature of at least 300 DEG C.
SYNTHESIS AND REACTIONS OF SOME PERFLUOROALKYL ETHER SUBSTITUTED SILANES
Chen, Grace J.,Tamborsky, Christ
, p. 313 - 322 (2007/10/02)
Perfluoroalkyl ether substituted silicon compounds of the type (CH3)nSi(RfORf)4-n (n=1-3) and HSi(RfORf)3 where RfORf=F(CF3)2COCF2CF2have been synthesized in good yields (64-81percent) through the reaction between the organolithium reagent RfORfLi and the corresponding silicon chloride.The stability of these compounds towards acid, base and aqueous media were studied and the ease of cleavage of the Si-RfORf bond was found to be in the order HSi(RfORf)3>CH3Si(RfORf)3>(CH3)2Si(RfORf)2>(CH3)3SiRfORf.The influence of the RfORf group on some properties of these compounds is also described.