232603-07-5

Basic information

• Product Name: ethyl (methyl-2,3,4-tri-O-benzyl-6,7-dideoxy-α-D-galactooctopyranosid)uronate
• Synonyms: ethyl (methyl-2,3,4-tri-O-benzyl-6,7-dideoxy-α-D-galactooctopyranosid)uronate
• CAS NO: 232603-07-5
• Molecular Weight: 534.65
• Mol File: 232603-07-5.mol

Chemical Properties

• CAS DataBase Reference: ethyl (methyl-2,3,4-tri-O-benzyl-6,7-dideoxy-α-D-galactooctopyranosid)uronate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (methyl-2,3,4-tri-O-benzyl-6,7-dideoxy-α-D-galactooctopyranosid)uronate(232603-07-5)
• EPA Substance Registry System: ethyl (methyl-2,3,4-tri-O-benzyl-6,7-dideoxy-α-D-galactooctopyranosid)uronate(232603-07-5)

Safety Data

• Hazardous Substances Data: 232603-07-5(Hazardous Substances Data)

Upstream product

• 134680-55-0 methyl 2,3,4-tri-O-benzyl-α-D-galacto-hexodialdo-1,5-pyranoside 
• 4356-80-3 methyl 2,3,4-tri-O-benzyl-α-D-galactopyranoside 

Downstream Products

• 302800-78-8 methyl 8-O-(3,4,6-tri-O-benzyl-1,2-dideoxy-D-xylo-hex-1-enyl)-6,7,9-trideoxy-α-D-galacto-nona-8-enopyranoside 
• 232603-17-7 methyl 8-O-(3,4,6-tri-O-benzyl-1,2-dideoxy-D-arabino-hex-1-enyl)-6,7,9-trideoxy-α-D-galacto-nona-8-enopyranoside 
• 232603-13-3 3,4,6-tri-O-benzyl-1,2-dideoxy-α-D-arabino-hex-1-enyl (methyl 2,3,4-tri-O-benzyl-6,7-dideoxy-α-D-galacto-octopyranosid)uronate 
• 232603-10-0 methyl-2,3,4-tri-O-benzyl-α-D-galactopyranosidocturonic acid 

Relevant articles and documents

Convergent preparation of 1,6-linked C-disaccharides via olefin metathesis

The DCC mediated coupling reaction of 3,4,6-tri-O-benzyl-1,2-dideoxy-D- arabino-hex-1-enitol (5a) with a variety of sugar based carboxylic acids 6a- d gave esters 7a-d in good yield. Methylenation of the formed esters led to the acyclic enol ethers 8a-d a

An olefin metathesis route for the preparation of (1 → 6)-linked C-disaccharide glycals. A convergent and flexible approach to C-saccharide synthesis

A convergent route to a variety of C-1-disaccharide glycals based on the olefin metathesis reaction of enol ethers and alkenes is described. The DCC-mediated coupling reaction of a variety of pentose enitols (1a-c) with a number of C-5- and C-6-monosaccharide carboxylic acids (2a-e) gave the corresponding esters 3a-1 in good yield. Methylenation of these compounds was followed by ring-closing metathesis, mediated by the Schrock molybdenum catalyst 8 in warm toluene, to provide the target C-disaccharide glycals 5a-1. The formed enol ether double bond in 5a was then transformed, via standard manipulations, into a variety of C-disaccharide derivatives 21-25.