23281-56-3

Usage

InChI:InChI=1/C11H15ClN2/c1-13-7-8-14(2)11(13)9-3-5-10(12)6-4-9/h3-6,11H,7-8H2,1-2H3

Upstream product

• 104-88-1 4-chlorobenzaldehyde 
• 110-70-3 N,N`-dimethylethylenediamine 

Downstream Products

• 162896-87-9 bis-(4,4′-formyl)benzophenone 
• 1571-08-0 methyl 4-formylbenzoate 
• 23229-37-0 1,3-dimethyl-2-phenylimidazolidine 
• 623-27-8 terephthalaldehyde, 
• 52010-95-4 4-(1-hydroxy-1-phenylmethyl)benzaldehyde 
• 102-11-4 N-benzyl-N-methyl-N'-methylethylenediamine 
• 59793-79-2 4-(1-hydroxy-2,2-dimethylpropyl) benzaldehyde 

Relevant academic research and scientific papers

Cyclopentyl methyl ether-NH4X: A novel solvent/catalyst system for low impact acetalization reactions

Cyclopentyl methyl ether, a low impact ether forming a positive azeotrope with water, was successfully employed as a solvent in the synthesis of 1,3-dioxanes and 1,3-dioxolanes carried out under Dean-Stark conditions by the acetalization of aliphatic and aromatic aldehydes or ketones, employing ammonium salts as environmentally friendly acidic catalysts.

Reductive lithiation of 1,3-dimethyl-2-arylimidazolidines

Naphthalene catalyzed lithiation of 1,3-dimethyl-2-phenylimidazolidine led to cleavage of the benzylic carbon-nitrogen bond, with formation of an intermediate dianion. Under similar conditions, 1,3-dimethyl-2-(4-chlorophenyl) imidazolidine underwent regioselective cleavage of the aromatic carbon-chlorine bond, leading to a 4-formylphenyllithium equivalent, whilst 1,3-dimethyl-2-(4- methoxymethylphenyl)imidazolidine underwent regioselective cleavage of the benzylic carbon-oxygen bond, leading to a 4-formylbenzyllithium equivalent.

Comparative radioprotective activity of various pentagonal compounds with two heteroatomes

Various heterocyclic compounds with two heteroatomes were synthesized and their potential radioprotective activity was tested. This study shows the interest of phenylthiazolidines derivatives in chemical radioprotection.