232932-77-3

Basic information

• Product Name: Bromomethyl-[1,1-diisopropyl-3-((S)-toluene-4-sulfinyl)-prop-2-ynyloxy]-dimethyl-silane
• CAS NO: 232932-77-3
• Molecular Weight: 429.494
• Mol File: 232932-77-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Bromomethyl-[1,1-diisopropyl-3-((S)-toluene-4-sulfinyl)-prop-2-ynyloxy]-dimethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: Bromomethyl-[1,1-diisopropyl-3-((S)-toluene-4-sulfinyl)-prop-2-ynyloxy]-dimethyl-silane(232932-77-3)
• EPA Substance Registry System: Bromomethyl-[1,1-diisopropyl-3-((S)-toluene-4-sulfinyl)-prop-2-ynyloxy]-dimethyl-silane(232932-77-3)

Safety Data

• Hazardous Substances Data: 232932-77-3(Hazardous Substances Data)

Upstream product

• 16532-02-8 bromomethyldimethylsilyl chloride 
• 232932-73-9 3-Isopropyl-4-methyl-1-((S)-toluene-4-sulfinyl)-pent-1-yn-3-ol 
• 50444-99-0 (1R,2S,5R)-menthyl-(S)-p-toluenesulfinate 

Relevant articles and documents

5-Endo-Trig Radical Cyclizations of Bromomethyldimethylsilyl Diisopropylpropargylic Ethers. A Highly Diastereoselective Access to Functionalized Cyclopentanes

An efficient radical sequence involving a 5-exo-dig, a diastereoselective 1,5-H transfer, and a rarely observed in an all-carbon system 5-endo-trig cyclization allows the construction of cyclopentyl derivatives 2 bearing four controlled stereogenic center