232932-78-4Relevant articles and documents
5-Endo-Trig Radical Cyclizations of Bromomethyldimethylsilyl Diisopropylpropargylic Ethers. A Highly Diastereoselective Access to Functionalized Cyclopentanes
Bogen, Stephane,Gulea, Mihaela,Fensterbank, Louis,Malacria, Max
, p. 4920 - 4925 (2007/10/03)
An efficient radical sequence involving a 5-exo-dig, a diastereoselective 1,5-H transfer, and a rarely observed in an all-carbon system 5-endo-trig cyclization allows the construction of cyclopentyl derivatives 2 bearing four controlled stereogenic center