23306-02-7Relevant academic research and scientific papers
Solution Photochemistry of Azulene
Selco, J. I.,Brooks, T.,Chang, M.,Trieu, M. T.,McDonald, J. K.,McManus, S. P.
, p. 429 - 433 (1994)
Photochemical reactivity has been observed in solution-phase azulene.Experiments are described which confirm photoinduced deuteration, chlorination, and polymerization.The threshold for the observed chemistry is at the origin of S2 which is at 27956 +/- 8 cm-1 (357.7 +/- 0.1 nm) in chloroform.Only one photon is required to induce the observed chlorine substitution reactions.Although no naphthalene is formed, this chemical channel appears to be the equivalent of a thermal reaction, with the substitutions taking place at the two equivalent positions on the small ring of azulene.The mechanism of these reactions is bimolecular in nature.Chlorination provides a complex mixture of products in most cases; however, deuteration proceeds cleanly giving only 1,3-d2-azulene.
Azulene – Thiophene – Cyanoacrylic acid dyes with donor-π-acceptor structures. Synthesis, characterisation and evaluation in dye-sensitized solar cells
Cowper, Paul,Pockett, Adam,Kociok-K?hn, Gabriele,Cameron, Petra J.,Lewis, Simon E.
supporting information, p. 2775 - 2786 (2018/05/04)
We report the synthesis of five new azulene containing dyes, having D-π-A type structures. These dyes are synthesised using a sulfonium salt cross-coupling reaction. The dyes have been evaluated spectroscopically, electrochemically, crystallographically, and as sensitizers in dye-sensitized solar cells. We propose a rationale for the dyes’ spectroscopic properties and performance in cells, based on conformational data derived from their crystal structures.
