234433-93-3Relevant academic research and scientific papers
One- and two-directional iterative 1,2-asymmetric induction in acyclic systems - Easy access to anti, anti and anti, syn dipropionate and diphenylacetate stereotriads
Hanessian, Stephen,Ma, Jianguo,Wang, Wengui
, p. 4627 - 4630 (2007/10/03)
Stereocontrolled addition of organocuprate reagents to γ-alkoxy-α,β- unsaturated esters can be done in one- and two-directional modes with excellent 1,2-induction. Enolate hydroxylations proceed with high diastereoselectivity affording acyclic chains with three to five contiguous stereogenic centers of the propionate and phenylpropionate triad types.
