23451-58-3Relevant academic research and scientific papers
Counterion effects in a gold-catalyzed synthesis of pyrroles from alkynyl aziridines
Davies, Paul W.,Martin, Nicolas
supporting information; experimental part, p. 2293 - 2296 (2009/10/02)
Aryl-substituted N-tosyl alkynyl aziridines undergo a gold-catalyzed ring expansion to afford 2,5-substituted pyrrole products. Under certain conditions, a ring-expansion and rearrangement leads to 2,4-substituted pyrroles. The reaction pathway is determi
A facile and regioselective synthesis of 2,5-disubstituted pyrroles via gold-catalyzed cycloisomerization of acetylenylaziridines
Chen, Dong-Dong,Hou, Xue-Long,Dai, Li-Xin
supporting information; experimental part, p. 6944 - 6946 (2010/02/27)
Gold-catalyzed cycloisomerization reaction of acetylenylaziridines provides 2,5-disubstituted pyrroles in high yields. The presence of protic species accelerates the reaction rate and improves the yields of pyrrole products.
