23456-88-4

Usage

Type of compound

Tetraazene derivative

Nitrogen atoms

Contains four nitrogen atoms in its structure

Usage

Primarily used in organic synthesis and as a reducing agent in chemical reactions

Physical state

Yellow crystalline solid

Odor

Strong odor

Reactivity

Highly reactive due to the presence of multiple double bonds in its structure

Potential applications

Materials science and medicinal chemistry

Safety concerns

Can pose health and safety risks if not properly managed

Handling

Should be handled with caution

Upstream product

• 5802-60-8 N,N-dibenzylhydrazine 

Downstream Products

• 780-25-6 N-benzylidene benzylamine 
• 103-49-1 dibenzylamine 

Relevant academic research and scientific papers

Oxidation of 1,1-disubstituted hydrazines with benzeneseleninic acid and selenium dioxide. Facile preparation of tetrazenes

Various 1,1-disubstituted hydrazines were oxidized with benzeneseleninic acid in methanol, generally producing the corresponding tetrazenes in high yield.Studies of the by-products of the reaction, of the effects of protic vs. aprotic solvents, and trapping experiments suggest that N-aminonitrenes are unlikely intermediates in this oxidation.An alternative mechanism involving a Pummerer-like reaction of seleninamides derived from the hydrazines is proposed.Tetrazene formation fails when the hydrazine precursor contains an aryl or p-toluenesulfonyl substiuent, or when it is highly hindered.Selenium dioxide may be employed as the oxidant instead of the seleninic acid, but is generally less efficacious in achieving high tetrazene yields.

Oxidation of 1,1-Disubstituted Hydrazines to Tetrazenes with Benzeneseleninic Acid

The oxidation of 1,1-disubstituted hydrazines with benzeneseleninic acid in methanol affords the corresponding tetrazenes in high yield.