234774-83-5Relevant academic research and scientific papers
Stereoselective formal [3 + 3] cycloaddition approach to cis-1-azadecalins and synthesis of (-)-4a,8a-diepi-pumiliotoxin C. Evidence for the first highly stereoselective 6π-electron electrocyclic ring closures of 1-azatrienes
Sklenicka, Heather M.,Hsung, Richard P.,McLaughlin, Michael J.,Wei, Lin-Li,Gerasyuto, Aleksey I.,Brennessel, William B.
, p. 10435 - 10442 (2007/10/03)
Evidence is described here to support that a highly stereoselective 6π-electron electrocyclic ring closure of 1-azatrienes is a key step in formal [3 + 3] cycloaddition or annulation reactions of chiral vinylogous amides with α,β-unsaturated iminium salts
Formal cycloaddition reactions of vinylogous amides with α,β-Unsaturated iminiums. A strategy for constructing piperidinyl heterocycles
Hsung, Richard P.,Wei, Lin-Li,Sklenicka, Heather M.,Douglas, Christopher J.,McLaughlin, Michael J.,Mulder, Jason A.,Yao, Letitia J.
, p. 509 - 512 (2008/02/11)
(Formula presented) A formal [3 + 3] cycloaddition strategy for constructing piperidinyl heterocycles from vinylogous amides and α,β-unsaturated iminiums is described here. These reactions proceed well, leading to various heterocycles that could serve as
