2350-11-0Relevant articles and documents
Chlorination of hydrocarbons with CCl4 catalyzed by complexes of Mn, Mo, V, Fe
Khusnutdinov,Shchadneva,Bayguzina,Oshnyakova,Mayakova,Dzhemilev
, p. 1557 - 1566 (2014/02/14)
Catalytic chlorination of alkanes, cycloalkanes, and adamantane utilizing tetrachloromethane as the source of chlorine and applying catalysts containing manganese, molybdenum, vanadium, and iron activated with nitrile ligands, alcohols, and water was fulfilled. The optimum ratios of catalysts and reagents and the best reaction conditions were found for selective synthesis of chlorine-substituted hydrocarbons derivatives. Pleiades Publishing, Ltd., 2013.
Photochlorination of n-Alkanes Adsorbed on Pentasil Zeolites
Turro, Nicholas J.,Fehlner, James R.,Hessler, Diane P.,Welsh, Kevin M.,Ruderman, Warren,et al.
, p. 3731 - 3735 (2007/10/02)
The photochlorination of n-alkanes adsorbed on pentasil zeolites proceeds with up to a 20-fold greater selectivity for the monochlorination of terminal methyl groups compared to the selectivity observed when the reaction is carried out in a homogeneous solution.This enhanced selectivity, which provides a novel means of synthesizing terminally functionalized linear alkanes, was found to be a function of the percent loading of the alkane on the zeolite, the zeolite's silicon to aluminum ratio, the percent conversion of the starting material, and the water content of the zeolite.
