2350-11-0Relevant academic research and scientific papers
Chlorination of hydrocarbons with CCl4 catalyzed by complexes of Mn, Mo, V, Fe
Khusnutdinov,Shchadneva,Bayguzina,Oshnyakova,Mayakova,Dzhemilev
, p. 1557 - 1566 (2014/02/14)
Catalytic chlorination of alkanes, cycloalkanes, and adamantane utilizing tetrachloromethane as the source of chlorine and applying catalysts containing manganese, molybdenum, vanadium, and iron activated with nitrile ligands, alcohols, and water was fulfilled. The optimum ratios of catalysts and reagents and the best reaction conditions were found for selective synthesis of chlorine-substituted hydrocarbons derivatives. Pleiades Publishing, Ltd., 2013.
A mild, phosphine-free method for the conversion of alcohols into halides (Cl, Br, I) via the corresponding O-alkyl isoureas
Li, Zhengning,Crosignani, Stefano,Linclau, Bruno
, p. 8143 - 8147 (2007/10/03)
A novel procedure for the conversion of primary and secondary alcohols into the corresponding alkyl chlorides, bromides and iodides is described. The transformation is high-yielding in the case of chlorides and bromides, tolerates a range of functional groups, and does not rely on the use of phosphines.
Photochlorination of n-Alkanes Adsorbed on Pentasil Zeolites
Turro, Nicholas J.,Fehlner, James R.,Hessler, Diane P.,Welsh, Kevin M.,Ruderman, Warren,et al.
, p. 3731 - 3735 (2007/10/02)
The photochlorination of n-alkanes adsorbed on pentasil zeolites proceeds with up to a 20-fold greater selectivity for the monochlorination of terminal methyl groups compared to the selectivity observed when the reaction is carried out in a homogeneous solution.This enhanced selectivity, which provides a novel means of synthesizing terminally functionalized linear alkanes, was found to be a function of the percent loading of the alkane on the zeolite, the zeolite's silicon to aluminum ratio, the percent conversion of the starting material, and the water content of the zeolite.
Azo Anions in Synthesis: α-Amino Carbanion Equivalents from t-Butyldiphenylmethylhydrazones
Baldwin, Jack E.,Adlington, Robert M.,Newington, Ian M.
, p. 176 - 178 (2007/10/02)
α-Amino carbanion equivalents (=C(1-)NH2) and α-hydrazino anion equivalents (=C(1-)NHNH2) are readily accessible from the C-alkylation products of t-butyldiphenylmethylhydrazones; these azoalkanes can be efficiently transformed into amines, hydrazines, and also alkanes under mild reaction conditions.
