235100-41-1

Upstream product

• 235100-38-6 (S)-1-(1,4-Dioxa-spiro[4.5]dec-2-yl)-propan-2-one 
• 98-59-9 p-toluenesulfonyl chloride 
• 235100-40-0 (2S,4R)-4-Methyl-6-trimethylsilanyl-hex-5-yne-1,2,4-triol 

Downstream Products

• 235100-42-2 Toluene-4-sulfonic acid (4S,6R)-2,2,6-trimethyl-6-trimethylsilanylethynyl-[1,3]dioxan-4-ylmethyl ester 
• 235100-44-4 tert-Butyl-{(E)-(1S,3R)-5-[2-((4S,6R)-6-ethynyl-2,2,6-trimethyl-[1,3]dioxan-4-ylmethyl)-[1,3]dithian-2-yl]-1,3-dimethyl-pent-4-enyloxy}-diphenyl-silane 
• 235100-45-5 (2S,4R)-1-{2-[(E)-(3R,5S)-5-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-hex-1-enyl]-[1,3]dithian-2-yl}-4-methyl-hex-5-yne-2,4-diol 
• 235100-46-6 (E)-(3R,5S,10R,12S)-12-(tert-Butyl-diphenyl-silanyloxy)-3,5-dihydroxy-3,10-dimethyl-tridec-8-en-1-yn-7-one 

Relevant academic research and scientific papers

Synthetic study on top-half (C14-C25) fragment of amphidinolide B, a 26-membered macrolide

The top-half fragment (C14-C25) of amphidinolide B, a potent cytotoxic macrolide isolated from the marine dinoflagellate Amphidinium sp., has been synthesized using a coupling reaction of iodide 16 corresponding to the C14