23556-91-4Relevant academic research and scientific papers
Highly selective isomerization of allyloxyalcohols to cyclic acetals or 1-propenyloxyalcohols
Urbala, Magdalena,Ku?nik, Nikodem,Krompiec, Stanis?aw,Rzepa, Józef
, p. 1203 - 1206 (2004)
Highly selective isomerization of allyloxyalcohols either to 1-propenyl derivatives or to cyclic acetals of propanal depending on the transition metal (Ru, Rh) complex used is described together with a proposed explanation of an alternative reaction, which permits broad application of the described method.
Raising the ceiling of diastereoselectivity in hydrogen transfer on acyclic radicals
Denissova, Irina,Maretti, Luca,Wilkes, Brian C.,Scaiano,Guindon, Yvan
supporting information; experimental part, p. 2438 - 2446 (2009/08/07)
We report here that the monodentate complexation of Me2AlCl to an ester group significantly enhances the selectivity of hydrogen transfer on acyclic radicals flanked by both an ester functionality and a stereogenic center, leading to C-2,C-3-an
A selective and convenient ruthenium mediated method for the synthesis of mixed acetals and orthoesters
Krompiec, Stanis?aw,Penczek, Robert,Ku?nik, Nikodem,Ma?ecki, Jan Grzegorz,Matlengiewicz, Marek
, p. 137 - 140 (2007/10/03)
Addition of alcohols and phenols to O-allyl compounds (allyl ethers and acrolein acetals), catalyzed by [RuCl2(PPh3)3], was examined. Intramolecular addition of an OH group, leading to the formation of cyclic acetals and o
