23575-27-1

Upstream product

• 62-53-3 aniline 

Downstream Products

• 103751-59-3 (C₆H₅NH₂)Co(C₄H₇N₂O₂)2(CH(CN)CH₂CN) 
• 14637-49-1 (C₆H₅NH₂)Co(C₄H₇N₂O₂)2(CH(CH₃)CN) 

Relevant academic research and scientific papers

Anhydrous trans-(aniline)chlorobis(dimethylglyoximato)cobalt(III)

The crystal structure of anhydrous tran5-(aniline)-chlorobis[dimethylglyoximato(1-)]cobalt(III), [CoCl-(C4H7N2O2)2(C 6H7N)], has been determined. The Co ion shows distorted octahedral coordination with the N atoms of the dimethylglyoximato ligands in the equatorial sites and the N atom of aniline and the Cl atom in the apical sites. From the values of the Co - N distances and the N - Co - N angles it is deduced that both equatorial ligands are dimethylglyoximato(1-), while in the previously determined dihydrated compound the protonation sites are such as to give a (dimethylglyoxime)[dimethylglyoximato(2-)]cobalt complex.