236110-88-6Relevant articles and documents
Tandem hydroformylation/aldol addition of silyl enol ethers bearing remote olefinic functionalities
Hollmann, Christoph,Eilbracht, Peter
, p. 1685 - 1692 (2000)
Rhodium(I) complex catalysed hydroformylation of unsaturated silyl enol ethers leads to products of an intramolecular aldol addition in a one-pot procedure. Thus β,γ- or γ,δ-unsaturated silyl enol ethers undergo tandem hydroformylation/Mukaiyama aldol reaction to form cyclic O-silylated aldol adducts with high selectivity and good yields. (C) 2000 Elsevier Science Ltd.