23643-63-2Relevant academic research and scientific papers
Study of sophoricoside derivatives with the aid of lanthanoid shift reagents
Turov,Bondarenko,Khilya
, p. 535 - 538 (1996)
Acylated and methylated derivatives of sophoricoside and of genistein have been synthesized, and their interaction in solution with the lanthanoid shift reagent (LSR) Eu(FOD)3 has been studied. For 5-O-alkyl derivatives of genistein an anomalous broadening of the 1H NMR signals was observed in the presence of the LSR, which is explained by the formation with the LSR of a chelate having a low rate of dissociation. The temperature and concentration dependencies of the paramagnetic broadenings of the signals have been studied.
