2369-21-3

Basic information

• Product Name: N-(2-fluorophenyl)hydroxylamine
• Synonyms: N-(2-fluorophenyl)hydroxylamine
• CAS NO: 2369-21-3
• Molecular Weight: 127.118
• Mol File: 2369-21-3.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: N-(2-fluorophenyl)hydroxylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-fluorophenyl)hydroxylamine(2369-21-3)
• EPA Substance Registry System: N-(2-fluorophenyl)hydroxylamine(2369-21-3)

Safety Data

• Hazardous Substances Data: 2369-21-3(Hazardous Substances Data)

Upstream product

• 348-54-9 2-Fluoroaniline 
• 1493-27-2 ortho-nitrofluorobenzene 

Downstream Products

• 90493-82-6 N-(2-Fluorophenyl)benzohydroxamic acid 
• 59478-03-4 3,3-dimethyl-1-(o-fluorophenyl)triazene-1-oxide 
• 858515-78-3 methyl 7-fluoro-1H-indole-3-carboxylate 
• 1403889-71-3 S-5-(acetoxy(2-fluorophenyl)amino)-5-oxo-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pentan-2-yl O-ethyl carbonodithioate 
• 1403889-70-2 S-5-(acetoxy(2-fluorophenyl)amino)-5-oxo-1-(2-oxocyclohexyl)pentan-2-yl O-ethyl carbonodithioate 
• 1403889-62-2 S-2-(acetoxy(2-fluorophenyl)amino)-2-oxoethyl O-ethyl carbonodithioate 
• 1403889-51-9 C₈H₇ClFNO₂ 
• 90493-88-2 2'-Chloro-6'-fluorobenzanilide 
• 363-51-9 2-chloro-6-fluoroaniline 

Relevant articles and documents

Redox-Neutral Selenium-Catalysed Isomerisation of para-Hydroxamic Acids into para-Aminophenols

A selenium-catalysed para-hydroxylation of N-aryl-hydroxamic acids is reported. Mechanistically, the reaction comprises an N?O bond cleavage and consecutive selenium-induced [2,3]-rearrangement to deliver para-hydroxyaniline derivatives. The mechanism is studied through both 18O-crossover experiments as well as quantum chemical calculations. This redox-neutral transformation provides an unconventional synthetic approach to para-aminophenols.

Regioselective installation of fluorosulfate (-OSO2F) functionality into aromatic C(sp2)-H bonds for the construction of: Para-amino-arylfluorosulfates

The construction of para-amino-arylfluorosulfates was achieved through installation of fluorosulfate (-OSO2F) functionality into aromatic C(sp2)-H bonds by the reaction of N-arylhydroxylamine with sulfuryl fluoride (SO2Fs

An unusual synthesis of N-unsubstituted benzazepinones

A short route to novel bicyclic N-unprotected benzazepinones is described starting from N-acetoxyanilides involving radical addition and cyclization with concomitant homolytic rupture of the N-O bond.