23695-65-0

Upstream product

• 107824-85-1 3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 122967-96-8 C₁₀H₁₄SGe(C₆H₂(CH₃)3)2 

Downstream Products

• 35357-08-5 C₁₉H₂₄S 
• 59556-34-2 2-(2-Phenyl-allylsulfanyl)-adamantane 
• 31934-34-6 2',5'-dihydrospiro 
• 31934-33-5 2',5'-dihydrospiro[adamantane-2,2'-(1,3,4)-thiadiazole] 
• 31934-34-6 C₁₁H₁₆N₂S 
• 31934-33-5 1,3,4-thiadiazoline-2-spiro-2'-adamantane 
• 700-58-3 2-Adamantanone 
• 31023-85-5 dispirodithietane-4',2''-adamantane> 
• 93490-40-5 C₁₅H₂₂OS 
• 95549-31-8 3-phenyl-[thiirane-2-spiro-2'-adamantane] 
• 93490-37-0 C₁₄H₂₀OS 
• 530-48-3 1,1-Diphenylethylene 
• 52146-63-1 dispiro[tricyclo[3.3.1.1]decane-2,3''-(1,2,4)-trithiolane-5',2'-tricyclo[3.3.1.1]decane] 
• 95549-23-8 3',5'-diphenyladamantane-2-spiro-2'-(1',3',4'-thiadiazoline) 

Relevant academic research and scientific papers

Thiones as superdipolarophiles. Rates and equilibria of nitrone cycloadditions to thioketones

1,3-Dipolar cycloadditions of N-methyl-C,C-diphenylnitrone (15) and N-methyl-C-phenylnitrone (16) with aliphatic thioketones are equilibrium reactions. The 1,4,2-oxathiazolidines were characterized and their dissociation constants measured by 1

Synthesis and chemistry of thiagermiranes

Dimethylgermylene (1) reacts with thioketones 3 and 9 to give 1,3,2,4-dithiadigermolanes 4 and 10, the ultimate products of formation of thiagermiranes 6 and 11 and subsequent addition of dimethylgermanethione (7). Dimesitylgermylene (16) reacts with adamantanethione (3) to give 3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane (18). Photolysis of thiagermirane 18 yields dimesitylgermylene (16) and adamantanethione (3) derived from germathiocarbonyl ylide 22. Oxidation of thiagermirane 18 by mCPBA gives 3-(2-adamantyl)-4,4-dimesityl-1,2,4-oxathiagermetane S-oxide (27). X-ray analyses were done for thiagermirane 18 and 1,2,4-oxathiagermetane S-oxide 27.