2370920-87-7Relevant academic research and scientific papers
Pyrene-based aggregation-induced emission luminogens (AIEgens) with less colour migration for anti-counterfeiting applications
Wang, Xiaohui,Wang, Lirong,Mao, Xiaoyu,Wang, Qingsong,Mu, Zhongfei,An, Li,Zhang, Wan,Feng, Xing,Redshaw, Carl,Cao, Changyong,Qin, Anjun,Tang, Ben Zhong
, p. 12828 - 12838 (2021)
Traditional luminescent materials are subject to aggregation-caused quenching, which limits their use for high-technological applications in the solid state. In an attempt to address such issues when using luminescent materials in fluorescent inks, by taking advantage of the aggregation-induced emission (AIE) behaviour, this article presents a set of pyrene-based AIEgens which possess high thermal stability, excellent fluorescence properties, and good biocompatibility. These AIEgens can be utilized as fluorescent inks for anti-counterfeiting applications at ultralow/low concentration (0.004-0.5 wt%) (weightAIEgens?:?weightbinder= 5?:?125?000-5?:?1000) with slight colour migration (27 nm) for different printing substrates. The use of such a fluorescent ink containing pyrene-based AIEgens has extended the scope of application over the range from ultralow to high concentration thereby avoiding the aggregation-caused quenching (ACQ) effect. Additionally, this system would lower the product cost, and be beneficial for the environment. The high-quality fluorescence pattern was found to exhibit good printability on different types of paper by old printing technology (screen printing technology). This work highlights that pyrene-based AIEgens are excellent candidates for use in anti-counterfeiting, and these results have the potential to enrich the practical applications of AIEgens in both academic and industrial fields.
Pyrene unit-containing organic fluorescent material with aggregation-induced emission as well as preparation method and application of pyrene unit-containing organic fluorescent material
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Paragraph 0051-0053, (2021/06/21)
The invention belongs to the field of fluorescent ink, and discloses a pyrene unit-containing organic fluorescent material with aggregation-induced emission as well as a preparation method and application of the pyrene unit-containing organic fluorescent material. The molecular structural formula of the organic fluorescent material is as shown in the specification, wherein the substitution position of a substituent group is at the 1-site or 2-site of a pyrene unit, the substituent group R1 or R2 is cyano, R3 substituent is selected from substituted aromatic hydrocarbon containing 5-30 carbon atoms, aryloxy containing 6-50 ring atoms, aromatic amine containing 5-30 carbon atoms, boron aromatic hydrocarbon containing 6-20 carbon atoms or aromatic heterocyclic group containing 5-40 carbon atoms, and m is more than or equal to 0 and less than or equal to 10. The organic fluorescent material provided by the invention has typical aggregation-induced emission properties, can realize printing of clear anti-counterfeiting patterns on different substrates, and is expected to be directly applied to the anti-counterfeiting field.
With aggregation induced organic semiconductor photocatalyst and its preparation method and application
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Paragraph 0026; 0045; 0046; 0047, (2019/07/10)
The invention belongs to the field of organic semiconductor material, discloses a with aggregation induced organic semiconductor photocatalyst and its preparation method and application. The photocatalyst is under inert atmosphere, four-phenyl ethylene fluoro derivatives as raw materials, adding phenyl acetonitrile derivative and organic alkali, in an organic solvent reaction; the molecular structural formula as shown in formula (I): Wherein R substituent is selected from 5 - 30 carbon atoms substituted aromatic hydrocarbon, containing 6 - 50 ring atoms of the aryloxy, containing 5 - 30 carbon atoms of the aromatic amine, containing 6 - 20 carbon atoms or [...] containing 5 - 40 carbon atoms of the aromatic heterocyclic group, the 1 ≤ n ≤ 10. The organic semiconductor photocatalyst containing four phenyl b dilute and its related derivatives, can be used for degrading the natural organic pollutants or artificial synthetic organic pollutants, the photocatalyst under the illumination condition, by mixing, stirring, can effectively degrade target pollutant.
