23733-47-3Relevant academic research and scientific papers
Copper-catalyzed cross-coupling of 1-haloalkyl-o-carboranes with Grignard reagents: An efficient route to monosubstituted o-carborane derivatives
Lu, Ju-You,Du, Yongmei,Zhao, Bo,Lu, Jian
supporting information, p. 161 - 169 (2015/12/23)
A convenient and efficient copper-catalyzed reaction has been developed for the synthesis of functionalized o-carborane derivatives by using a Cu/phosphine catalytic system. Cross-coupling of readily available 1-haloalkyl-o-carboranes with Grignard reagents proceeds efficiently under mild conditions, and the corresponding monosubstituted o-carboranes were obtained in good to excellent yields.
