23784-45-4Relevant academic research and scientific papers
Generation of alkyl radicals from alkylsilyl peroxides and their applications to C-N or C-O bond formations
Sakurai, Shunya,Kato, Terumasa,Sakamoto, Ryu,Maruoka, Keiji
, p. 172 - 179 (2018/12/11)
This article describes a novel method for the generation of alkyl radicals from alkylsilyl peroxides and their applications to the Cu-catalyzed mono-N-alkylation of amides or arylamines, and to the O-alkylation of carboxylic acids. The use of alkylsilyl peroxides as alkyl radical sources includes the following synthetic advantages: i) various alkylsilyl peroxides can be readily synthesized from the corresponding alcohols and be stored at bench, and ii) a variety of alkyl radicals can be generated efficiently under mild conditions.
INTRAMOLECULAR RADICAL TRAPPING IN "SET" RING OPENING OF N-ENOYL AZIRIDINES. A NEW MECHANISTIC PROBE AND A NEW SYNTESIS OF PYRROLIDONES.
Bentz, G.,Besbes, N.,Laurent, A.,Stamm, H.
, p. 2511 - 2512 (2007/10/02)
N-Acryloyl aziridines 1a-c form pyrrolidones 4a-c via electron attachment, homolytic ring cleavage of the intermediate ketyl, and intramolecular trapping of the radical by the C=C bond of the acryloyl moiety of 1a-c.
