23825-24-3Relevant academic research and scientific papers
Reductive double alkylation of anthracene with lithium bromoacetate; synthesis of cyclopentaceanthrylene, a novel dicyclopenta-fused hydrocarbon
Boere, Ben B.,Mulder, Patrick P. J.,Cornelisse, Jan,Lugtenburg, Johan
, p. 463 - 466 (2007/10/02)
The synthesis and characterization of cyclopentaceanthrylene, a novel dicyclopenta-fused polycyclic hydrocarbon, are described.The key step is the reductive double alkylation of anthracene by lithium bromoacetate in liquid ammonia giving cis-9,10-dihydroanthracene-9,10-diacetic acid in good yield.Lithium bromoacetate is a better alkylating agent than the sodium iodoacetate formerly used.
