238401-89-3Relevant academic research and scientific papers
Unexpected epimerization at C2 in the Horner-Wadsworth-Emmons reaction of chiral 2-substituted-4-oxopiperidines
Etayo, Pablo,Badorrey, Ramon,Diaz-De-Villegas, Maria D.,Galvez, Jose A.
, p. 3420 - 3422 (2006)
The observed epimerization at C2 in the Horner-Wadsworth-Emmons (HWE) reaction of chiral 2-substituted-4-oxopiperidines has been investigated and, on the basis of the experimental results, a mechanism for this unexpected process has been propos
Study of the reaction of imines derived from (R)-glyceraldehyde with Danishefsky's diene
Badorrey, Ramon,Cativiela, Carlos,Diaz-de-Villegas, Maria D.,Galvez, Jose A.
, p. 7601 - 7612 (2007/10/03)
N-Benzylimines derived from conveniently protected (R)-glyceraldehyde underwent diastereoselective tandem Mannich-Michael reaction with Danishefsky's diene in the presence of Lewis acids. The temperature, catalyst and solvent dependence of the product rat
