23868-11-3

Basic information

• Product Name: Benzoic acid, 2-(phenylaMino)-, ethyl ester
• Synonyms: Benzoic acid, 2-(phenylaMino)-, ethyl ester;Ethyl 2-(phenylamino)benzoate
• CAS NO: 23868-11-3
• Molecular Formula: C₁₅H₁₅NO₂
• Molecular Weight: 241.2851
• EINECS: -0
• Mol File: 23868-11-3.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• Storage Temp.: 2-8°C
• CAS DataBase Reference: Benzoic acid, 2-(phenylaMino)-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2-(phenylaMino)-, ethyl ester(23868-11-3)
• EPA Substance Registry System: Benzoic acid, 2-(phenylaMino)-, ethyl ester(23868-11-3)

Safety Data

• Hazardous Substances Data: 23868-11-3(Hazardous Substances Data)

Upstream product

• 172216-91-0 α,α,α-trifluoro-N-phenyl-o-acetotoluidide 
• 930-68-7 cyclohexenone 
• 87-25-2 2-ethoxycarbonylaniline 
• 62-53-3 aniline 
• 100-47-0 benzonitrile 
• 586-96-9 Nitrosobenzene 
• 825-60-5 benzimidic acid ethyl ester 
• 172217-04-8 α,α,α-trifluoro-o-diacetotoluidide 
• 103-84-4 Acetanilid 
• 344-62-7 N-[2-(trifluoromethyl)phenyl]acetamide 
• 108-86-1 bromobenzene 
• 64-17-5 ethanol 
• 19263-30-0 3-phenyl-1,2,3-benzotriazin-4(3H)-one 
• 91-40-7 2-(phenylamino)benzoic acid 

Downstream Products

• 1026402-89-0 2-[(2-Ethoxycarbonyl-acetyl)-phenyl-amino]-benzoic acid ethyl ester 
• 1446358-27-5 11,11-diphenyl-10,11-dihydro-5H-dibenzo[b,f]azepine 
• 21737-58-6 10,11-dihydro-5H-dibenzo[b,f]azepin-10-one 
• 1446358-22-0 2-(2-(N-phenyl-N-tosylamino)phenyl)acetic acid 
• 1446358-18-4 2-(2-(N-phenyl-N-tosylamino)phenyl)-1,1-diphenylethanol 
• 1446358-17-3 3-(2-(N-phenyl-N-tosylamino)benzyl)pentan-3-ol 
• 1446358-16-2 1-(2-(N-phenyl-N-tosylamino)phenyl)-2-methylpropan-2-ol 
• 1446358-14-0 ethyl 2-(2-(N-phenyl-N-tosylamino)phenyl)acetate 
• 1194821-23-2 ethyl 2-(2-(phenylamino)phenyl)acetate 
• 1446358-11-7 2-(2-(phenylamino)phenyl)acetonitrile 
• 1446358-09-3 N-(2-(chloromethyl)phenyl)benzenamine 
• 53044-24-9 N-Phenyl-o-(hydroxymethyl)aniline 
• 494-19-9 9,10-dihydrodibenzazepine 
• 23857-22-9 2-ethoxy-1-phenyl-2-thioxo-1,2-dihydro-2λ⁵-benzo[d][1,3,2]thiazaphosphinine-4-thione 

Relevant articles and documents

Synthesis of 1H-Indazoles from Imidates and Nitrosobenzenes via Synergistic Rhodium/Copper Catalysis

Nitrosobenzenes have been used as a convenient aminating reagent for the efficient synthesis of 1H-indazoles via rhodium and copper catalyzed C-H activation and C-N/N-N coupling. The reaction occurred under redox-neutral conditions with high efficiency and functional group tolerance. Moreover, a rhodacyclic imidate complex has been identified as a key intermediate.

Metal-free direct amination/aromatization of 2-cyclohexenones to iodo-N-arylanilines and N-arylanilines promoted by iodine

An iodine mediated aromatization leading to a one-pot synthesis of iodo-N-arylanilines and N-arylanilines is reported. This highly regioselective aliphatic-aromatic transformation can be performed with various combinations of 2-cyclohexenones and anilines. The presence of a directing group is crucial for achieving high yields.

Synthesis of 1,4 dihydro 4 methyl 1 phenyl 5H 1,3,4 benzotriazepin 5 ones

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