238736-49-7Relevant academic research and scientific papers
Electrochemical cleavage of allyl aryl ethers and allylation of carbonyl compounds: Umpolung of allyl-palladium species
Franco,Panyella,Rocamora,Gomez,Clinet,Muller,Dunach
, p. 5685 - 5688 (1999)
The electrochemical, Pd-catalyzed cleavage of the C-O bond of allyl aryl ethers has been examined; the method constitutes a new alternative for allyl ether deprotection. The allyl transfer from the allyl ether to the carbonyl group in 2-allyloxy benzaldehydes is reported and is an example of allyl-Pd reactivity umpolung. Pd(II) complexes, associated to several nitrogen ligands are efficient catalyst precursors for these electrochemical reactions.
Indium mediated allylation of β-chloro-/β-alkoxy vinylaldehyde: A facile one pot synthesis of 1-chloro-/1-alkoxy hexa-1,5-diene-3-ol derivatives
Pan, Dipanjan,Kar, Gandhi K.,Ray, Jayanta K.
, p. 1 - 9 (2003)
Indium mediated allylation of β-chloro- or β-alkoxy vinylaldehydes in the presence of sodium iodide produce homoallylic alcohol derivatives (1-chloro-/1-alkoxy hexa-1,5-diene-3-ol derivatives) in good yields.
Synthesis of enantiomerically pure cycloalkenols via combination strategy of enzyme-catalyzed reaction and RCM reaction
Shi-Hui, Han,Hirakawa, Takuya,Fukuba, Takaaki,Hayase, Shuichi,Kawatsura, Motoi,Itoh, Toshiyuki
, p. 2484 - 2490 (2008/03/13)
The preparation of three types of cyclic alkenols, (S)-2-cyclohexenol, (R)-2,5-dihydrobenzo[b]oxepin-5-ol, and (R)-5,6-dihydro-2H-benzo[b]oxocin-6-ol, has been accomplished in enantiomerically pure forms as model compounds using a combination of a lipase-catalyzed reaction and a ring closing olefin metathesis (RCM) reaction.
