238737-17-2Relevant academic research and scientific papers
Re-Silane complexes as frustrated lewis pairs for catalytic hydrosilylation
Abrahamse, Michael,Brown, Caleb A.,Ison, Elon A.
, p. 11403 - 11411 (2020/09/02)
A pathway for the catalytic hydrosilylation of carbonyl substrates with M(C6F5)3 (M = B, Al and Ga) was calculated by DFT (B3PW91-D3) and it was shown that in the case of the Al reagent, the carbonyl substrate binds irreversibly and inhibits catalysis by
Facile catalytic hydrosilylation of pyridines
Gutsulyak, Dmitry V.,Van Der Est, Art,Nikonov, Georgii I.
, p. 1384 - 1387 (2011/04/21)
Not only surprisingly facile, a hydrosilylation of pyridines under the catalysis of [Cp(iPr3P)Ru(NCCH3)2]+ has the advantages that it is 1,4-regioselective and reversible. The products can be transformed in a variety of ways (see scheme). The related complex [CpRu(NCCH3)3]+ catalyzes the two-hydrogen-atom reduction of phenanthroline by HSiMe2Ph/water.
1,4-Hydrosilylation of pyridine by ruthenium catalyst: A new reaction and mechanism
Osakada, Kohtaro
scheme or table, p. 3845 - 3846 (2011/06/24)
Making introductions: A half-sandwich Ru complex catalyzes the hydrosilylation of pyridine derivatives to produce N-silyl-3-hydropyridine through a 1,4-addition of the Si-H group (see scheme). The reversibility of the hydrosilylation was suggested based on the experimental results.
Chemoselective catalytic hydrosilylation of nitriles
Gutsulyak, Dmitry V.,Nikonov, Georgii I.
supporting information; experimental part, p. 7553 - 7556 (2010/12/19)
Well-behaved: The ruthenium complex [Cp(iPr3P)Ru(NCCH 3)2]+ (Cp=cyclopentadienyl) catalyzes monohydrosilylation of nitriles (see scheme) with unprecedented tolerance of most common functional groups. The catalyst is easily synthesized starting from commercially available compounds, is air-stable, recyclable, and works under solvent-free conditions.
