238737-17-2Relevant academic research and scientific papers
Re-Silane complexes as frustrated lewis pairs for catalytic hydrosilylation
Abrahamse, Michael,Brown, Caleb A.,Ison, Elon A.
, p. 11403 - 11411 (2020/09/02)
A pathway for the catalytic hydrosilylation of carbonyl substrates with M(C6F5)3 (M = B, Al and Ga) was calculated by DFT (B3PW91-D3) and it was shown that in the case of the Al reagent, the carbonyl substrate binds irreversibly and inhibits catalysis by
1,4-Hydrosilylation of pyridine by ruthenium catalyst: A new reaction and mechanism
Osakada, Kohtaro
scheme or table, p. 3845 - 3846 (2011/06/24)
Making introductions: A half-sandwich Ru complex catalyzes the hydrosilylation of pyridine derivatives to produce N-silyl-3-hydropyridine through a 1,4-addition of the Si-H group (see scheme). The reversibility of the hydrosilylation was suggested based on the experimental results.
Facile catalytic hydrosilylation of pyridines
Gutsulyak, Dmitry V.,Van Der Est, Art,Nikonov, Georgii I.
, p. 1384 - 1387 (2011/04/21)
Not only surprisingly facile, a hydrosilylation of pyridines under the catalysis of [Cp(iPr3P)Ru(NCCH3)2]+ has the advantages that it is 1,4-regioselective and reversible. The products can be transformed in a variety of ways (see scheme). The related complex [CpRu(NCCH3)3]+ catalyzes the two-hydrogen-atom reduction of phenanthroline by HSiMe2Ph/water.
Chemoselective catalytic hydrosilylation of nitriles
Gutsulyak, Dmitry V.,Nikonov, Georgii I.
supporting information; experimental part, p. 7553 - 7556 (2010/12/19)
Well-behaved: The ruthenium complex [Cp(iPr3P)Ru(NCCH 3)2]+ (Cp=cyclopentadienyl) catalyzes monohydrosilylation of nitriles (see scheme) with unprecedented tolerance of most common functional groups. The catalyst is easily synthesized starting from commercially available compounds, is air-stable, recyclable, and works under solvent-free conditions.
