238748-87-3

Upstream product

• 1138-80-3 N-(Benzyloxycarbonyl)glycine 
• 16707-70-3 2-(((benzyloxy)carbonyl)amino)ethanethioic S-acid 
• 238748-85-1 benzyl N-<2-<<1,1-dimethyl-2--2-thioxoethyl>amino>-2-oxoethyl>carbamate 

Downstream Products

• 457058-53-6 (2S,3S)-2-[2-({[(benzyloxy)carbonyl]amino}ethanethioamido)-2-methylpropanamido]-3-methylpentanoic acid 
• 457058-63-8 methyl (2S,3S)-2-[2-({[(benzyloxy)carbonyl]amino}ethanethioamido)-2-methylpropanamido]-3-methylpentanoate 
• 457058-51-4 benzyl N-[1-(4,5-dihydro-4,4-dimethyl-5-oxo-1,3-thiazol-2-yl)methyl]carbamate 

Relevant academic research and scientific papers

A novel acid-catalyzed isomerization of Aib-containing thiodipeptides

The use of amino thioacids in the 'azirine/oxazolone method' led to completely epimerized Aib-containing endothiodipeptides (Aib=2- aminoisobutyric acid). It could be established that the epimerization occurred during the acidic hydrolysis of the primaril