238757-51-2

Upstream product

• 171231-72-4 endo-3-benzyloxy-endo,endo-2,4-dimethyl-exo-6-hydroxy-8-oxabicyclo[3.2.1]octane 
• 760978-01-6 endo-3-benzyloxy-endo,endo-2,4-dimethyl-8-oxabicyclo-[3.2.1]-octan-6-one 
• 96691-92-8 (1R,2R,3r,4S,5S)-3-(benzyloxy)-2,4-dimethyl-8-oxa-bicyclo[3.2.1]oct-6-ene 

Downstream Products

• 1197360-31-8 C₁₇H₂₂O₄ 
• 1261156-44-8 (4S)-7-(benzyloxy)-4-allyl-6,8-dimethyl-2,9-dioxabicyclo[3.3.1]nonan-3-one 
• 1403660-65-0 (2R,3R,4S)-3-(benzyloxy)-4-((R)-2,2-dimethyl-1,3-dioxan-4-yl)-2-methylpentyl pivalate 
• 1403660-75-2 (2R,3R,4S,5R)-3-(benzyloxy)-5,7-dihydroxy-2,4-dimethylheptyl pivalate 
• 1403660-66-1 (2R,3R,4S,5R)-3-(benzyloxy)-7-(tert-butyldimethylsilyloxy)-5-hydroxy-2,4-dimethylheptyl pivalate 
• 1322669-24-8 C₂₄H₄₄O₃Si 
• 1322669-23-7 (2R,3R,4R,5R,6R)-3-(benzyloxy)-5-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-2,4-dimethyl-6-([(4-methylphenyl)sulfonyl]oxymethyl)octyl pivalate 
• 1322669-29-3 C₃₀H₄₄O₇S 
• 1322669-22-6 C₂₃H₃₈O₅ 

Relevant academic research and scientific papers

Studies towards the total synthesis of (-)-callystatin A

The synthesis of C1-C12 and C13-C 22 fragments of (-)-callystatin A is accomplished employing desymmetrization strategy for the creation of five chiral centres of the polypropionate fragment and application of c

Synthesis of C15-C27 segment of venturicidine X by utilizing desymmetrization protocol

We have achieved the synthesis of C15-C27 fragment of venturicidine X using desymmetrization protocol, substrate-controlled Grignard reaction, Barton-McCombie reaction, Sharpless epoxidation, and TBSOTf-mediated rearrangement to produce the aldol product

Formal total synthesis of (-)-saliniketals

(Chemical Equation Presented) A highly stereoselective formal total synthesis of the ornithine decarboxylase inhibitors (-)-saliniketals A and B is described. The salient features of the synthesis are the utilization of a desymmetrization technique to cre

A stereoselective synthesis of the C20-C32 fragment of the phorboxazoles

The C20-C32 fragment of the phorboxazoles was realized in a stereoconvergent manner utilizing a desymmetrization approach. This successful strategy involves epimerization and modified Julia olefination as key steps. Georg Thieme Verlag Stuttgart.

An efficient synthesis of (+)-prelactone B

An enantioselective synthesis of (+)-prelactone B 1 has been achieved on a multigram scale starting from a known bicyclic precursor 2. The key feature of the strategy is the generation of 3-stereogenic centres from a single bicyclic precursor, which has b

A stereoconvergent synthesis of the C(19)-C(31) fragment of scytophycin C

The C(19)-C(31) fragment of the anti-tumor macrolide, scytophycin C, was realized in a stereoconvergent manner utilizing a desymmetrization approach to create eight contiguous asymmetric centers from a common precursor.