23879-22-3Relevant articles and documents
Synthesis of tertiary sec-alkylamines by the addition of grignard reagents to N,N-dialkylformamides mediated by Ti(OiPr)4 and Me3SiCl
Tomashenko, Olesya,Sokolov, Viktor,Tomashevskiy, Alexander,Buchholz, Herwig A.,Welz-Biermann, Urs,Chaplinski, Vladimir,De Meijere, Armin
experimental part, p. 5107 - 5111 (2009/06/17)
A number of tertiary sec-alkylamines (22 examples, 29-80% yield) have been prepared according to a simple one-pot procedure by the addition of Grignard reagents to N,N-dialkylformamides in the presence of Ti(OiPr)4 and Me3SiCl. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.