2388-74-1

Basic information

• Product Name: 3-METHOXY THIOANISOLE
• Synonyms: 3-METHOXY THIOANISOLE;3-METHOXY THIOANISOLE 99%MIN;(3-methoxyphenyl)(methyl)sulfane;1-(Methylthio)-3-methoxybenzene;1-Methoxy-3-(methylthio)benzene;1-Methylthio-3-methoxybenzene;Methyl (3-methoxyphenyl) sulfide;Methyl [3-(methylthio)phenyl] ether
• CAS NO: 2388-74-1
• Molecular Formula: C₈H₁₀OS
• Molecular Weight: 154.23
• Mol File: 2388-74-1.mol
• Article Data: 20

Chemical Properties

• Boiling Point: 127 °C / 18mmHg
• Flash Point: 93 °C
• Appearance: /
• Density: 1.12
• Refractive Index: 1.5820 to 1.5860
• CAS DataBase Reference: 3-METHOXY THIOANISOLE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-METHOXY THIOANISOLE(2388-74-1)
• EPA Substance Registry System: 3-METHOXY THIOANISOLE(2388-74-1)

Safety Data

• Hazard Codes: Xi
• HazardClass: IRRITANT, STENCH
• Hazardous Substances Data: 2388-74-1(Hazardous Substances Data)

Usage

General Description

3-Methoxy Thioanisole is a chemical compound known for its organosulfur and phenolic properties. Usually appearing as a clear and colorless liquid, it has a distinct odor and is capable of dissolving in numerous organic solvents. It is commonly used in manufacturing and research settings, specifically as a reagent in organic synthesis. As with any chemical, precautions should be taken when handling 3-Methoxy Thioanisole due to its potential hazards such as causing skin irritation and serious eye damage. Therefore, protective gear including gloves and eye protection should be worn when handling this chemical.

InChI:InChI=1/C8H10O2S/c1-9-7-4-3-5-8(6-7)11-10-2/h3-6H,1-2H3

Upstream product

• 274928-75-5 1-methanesulfinyl-3-methoxy-benzene 
• 15570-12-4 3-methoxybenzenethiol 
• 74-88-4 methyl iodide 
• 13532-18-8 methyl 3-(methylthio)propionate 
• 66107-33-3 3-methoxyphenyl triflate 
• 624-92-0 Dimethyldisulphide 
• 766-85-8 3-methoxy-1-iodobenzene 
• 3463-03-4 3-methylsulfanylphenol 
• 2398-37-0 3-methoxyphenyl bromide 
• 616-38-6 carbonic acid dimethyl ester 
• 67-68-5 dimethyl sulfoxide 
• 541-73-1 1,3-Dichlorobenzene 
• 40167-20-2 N-(methylthio)phthalimide 
• 10365-98-7 3-methoxyphenylboronic acid 

Downstream Products

• 1657-85-8 (2,4-dinitro-phenyl)-(4-methoxy-2-methylsulfanyl-phenyl)-diazene 
• 63762-91-4 2-<(3-Methoxyphenyl)thio>-1-phenylethanone 
• 38474-02-1 1-(Ethylthio)-3-methoxybenzene 
• 85428-52-0 m-(ethanethio)phenetole 
• 82961-61-3 2-methoxy-6-methylsulfanyl-toluene 
• 85428-46-2 1-(Ethylthio)-3-methoxy-2-methylbenzene 
• 274928-75-5 1-methanesulfinyl-3-methoxy-benzene 
• 64-19-7 acetic acid 
• 83782-26-7 2-(((3-methoxyphenyl)thio)methyl)pyridine 
• 325142-84-5 3-methoxyphenylboronic acid pinacol ester 
• 95278-09-4 (3-methoxylphenyl)diphenylphosphine oxide 

Relevant articles and documents

Pd-Catalyzed Intermolecular Transthiolation of Ar-OTf Using Methyl 3-(Methylthio) Propanoate as a Thiol Surrogate

A method for the odorless synthesis of unsymmetrical sulfides via Csp2?O and Csp3?S bond activation is presented. Using methyl 3-(methylthio) propanoate as a MeSH surrogate, a series of substituted aryl methyl sulfides have been obtained in moderate to good yields. This catalytic protocol can also tolerate methyl 3-(methylthio)propionate derivatives to afford the corresponding aryl sulfides.

FORMIMIDAMIDINE COMPOUNDS USEFUL AGAINST PHYTOPATHOGENIC MICROORGANISMS

The present invention relates to 4-substituted amidine derivatives of the general formula (I), wherein A1-A4, D, L, Q, R7, R7' and integer's v and w have the meanings as defined in description. The invention further relates to methods for their preparation and use of said compounds to fight undesired phytopathogenic microorganisms, and agents for said purpose, comprising said amidine derivatives, all according to the invention. This invention further relates to a method for controlling undesired phytopathogenic microorganisms by application of said 4-substituted amidine derivatives of general formula (I) to such undesired microorganisms and/or to their habitat, according to the invention. (I)

N-Imidazolylation of Sulfoximines from N-Cyano Sulfoximines, 1-Alkynes, and N-Sulfonyl Azides

The rhodium-catalyzed N-imidazolylation of N-sulfonyl-1,2,3-triazoles with a variety of N-cyano sulfoximines has been developed for the synthesis of N-imidazolyl sulfoximines via elimination of molecular nitrogen. Copper-catalyzed [3+2] cycloaddition followed by rhodium-catalyzed N-imidazolylation from 1-alkynes, N-sulfonyl azides, and N-cyano sulfoximines is also demonstrated for the synthesis of N-imidazolyl sulfoximines in a one-pot procedure.