23906-87-8

Usage

Uses

Used in Organic Synthesis:
Tricyclo[3.3.1.1~3,7~]dec-1-ylphosphonic dichloride is utilized as a key intermediate in the synthesis of phosphorus-containing compounds, which are essential in various chemical reactions and the formation of complex organic molecules.
Used in Materials Science:
In the field of materials science, tricyclo[3.3.1.1~3,7~]dec-1-ylphosphonic dichloride may be employed as a component in the development of new materials with unique properties, such as those with enhanced thermal stability or specific catalytic activities.
Used in Pharmaceutical Industry:
Tricyclo[3.3.1.1~3,7~]dec-1-ylphosphonic dichloride could be used as a building block in the creation of pharmaceutical compounds, particularly those that require phosphorus in their molecular structure for biological activity.
Used in Chemical Research:
As a novel compound, tricyclo[3.3.1.1~3,7~]dec-1-ylphosphonic dichloride is likely to be a subject of interest in chemical research, where it may be studied for its reactivity, stability, and potential to form new types of chemical bonds or structures.

Upstream product

• 768-90-1 1-Adamantyl bromide 
• 281-23-2 adamantane 
• 768-95-6 1-adamanthanol 
• 700-57-2 1-adamantanol 
• 32314-61-7 1-nitroxyadamantane 
• 700-57-2 2-hydroxytricyclo<3.3.1.1^3,7>decane 
• 935-56-8 1-chloroadamantane 
• 58652-54-3 1-adamantyl trifluoroacetate 

Downstream Products

• 97745-35-2 1-adamantyl-O,O-diphenylphosphonate 
• 60509-83-3 (adamantan-1-yl)diphenylphosphine oxide 

Relevant academic research and scientific papers

Optimised synthesis and characterisation of 1-adamantyltrimethylphosphonium iodide

A synthetic route to multigram quantities of 1-adamantyltrimethylphosphonium iodide is reported. The synthesis starts from the commercially available precursor 1-adamantyl bromide and was optimised with respect to yield and ease of purification. The title compound is of interest to zeolite chemists as a potent organic structure-directing agent. Full spectroscopic characterisation data of all isolated intermediates and single crystal X-ray diffraction data of AdP(O)Cl2, [AdPMe2H]I and [AdPMe3]I (Ad?=?1-adamantyl) are reported.

Dichlorophosphorylation of adamantanols and 1-adamantylcarbinols in trifluoroacetic acid

A convenient method for dichlorophosphorylation of adamantanols and 1-adamantyl alcohols with phosphorus trichloride in trifluoroacetic acid is described. The dichlorophosphoryl group is selectively introduced to the different positions of the adamantane

A Convenient Method for the Synthesis of 1-Adamantyldichlorophosphine

1-Adamantyldichlorophosphine is obtained in good yield by reduction of 1-adamantyldichlorophosphine sulfide with triphenylphosphine in toluene.It can be quantitatively reduced to 1-adamantylphosphine with lithium alanate in ether.

Defying Stereotypes with Nanodiamonds: Stable Primary Diamondoid Phosphines

Direct unequal C-H bond difunctionalization of phosphorylated diamantane was achieved in high yield from the corresponding phosphonates. Reduction of the functionalized phosphonates provides access to novel primary and secondary alkyl/aryl diamantane phos

Recognition characteristics of an adaptive vesicular assembly of amphiphilic baskets for selective detection and mitigation of toxic nerve agents

We used isothermal titration calorimetry to investigate the affinity of basket 1 (470 ?3) for trapping variously sized and shaped organophosphonates (OPs) 2-12 (137-244 ?3) in water at 298.0 K. The encapsulation is, in each case, dri

Phosphorylation of Adamantane and its Derivatives in Trifluoroacetic Acid Medium

The possibility of dichlorophosphorylation of the carcass compounds of the adamantane series and of aryl(alkyl)carbinols, with phosphorus trichloride in the low-nucleophilicity trifluoroacetic acid medium was first demonstrated. A new preparative method for introducing a POCl2 group into the bridgehead and bridge positions of the adamantane nucleus, as well as into the α position of the side chain was developed. Some intermediate adamantyl cations may undergo isometizations, among them skeleton ones. A mechanism of the phosphorylation was proposed.

PHOSPHORYLATED ADAMANTANES. XV. PHOSPHORYLATION OF ADAMANTANE WITH P(III) ACID CHLORIDES IN SULFURIC ACID

A new method of introduction of a phosphoryl group into the nodal position of the adamantane nucleus was developed, in which sulfuric acid was used instead of aluminum halides to generate the adamantyl cation in reactions of Br-, OH-, and ONO2-substituted adamantanes and phosphonous and phosphorous chlorides. Relative rates of the hydride shift and skeletal isomerization were qualitatively estimated. Under comparable conditions the rate of the hydride shift in 2-adamantyl carbocation -> 1-adamantyl carbocation is substantially higher than that in the isomerization 1-ethyl-3-adamantyl carbocation -> 1,3-dimethyl-5-adamantyl carbocation.