23906-87-8

Basic information

• Product Name: tricyclo[3.3.1.1~3,7~]dec-1-ylphosphonic dichloride
• Synonyms: Phosphonic dichloride, 1-adamantyl-
• CAS NO: 23906-87-8
• Molecular Formula: C₁₀H₁₅Cl₂OP
• Molecular Weight: 253.1053
• Mol File: 23906-87-8.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 327.2°C at 760 mmHg
• Flash Point: 151.7°C
• Density: 1.33g/cm³
• Vapor Pressure: 0.000392mmHg at 25°C
• Refractive Index: 1.532
• CAS DataBase Reference: tricyclo[3.3.1.1~3,7~]dec-1-ylphosphonic dichloride(CAS DataBase Reference)
• NIST Chemistry Reference: tricyclo[3.3.1.1~3,7~]dec-1-ylphosphonic dichloride(23906-87-8)
• EPA Substance Registry System: tricyclo[3.3.1.1~3,7~]dec-1-ylphosphonic dichloride(23906-87-8)

Safety Data

• Hazardous Substances Data: 23906-87-8(Hazardous Substances Data)

Usage

General Description

"Tricyclo[3.3.1.1~3,7~]dec-1-ylphosphonic dichloride" is a chemical compound with the molecular formula C10H16Cl2OP. It is a phosphonic dichloride derivative of tricyclo[3.3.1.1~3,7~]decane, which is a bicyclic hydrocarbon. tricyclo[3.3.1.1~3,7~]dec-1-ylphosphonic dichloride is likely to be an important intermediate in the synthesis of various phosphorus-containing compounds, and it may have potential applications in organic synthesis and materials science. The exact properties and uses of this chemical may vary depending on the specific application and synthesis route, and further research and testing would be needed to fully understand its potential.

Upstream product

• 700-57-2 2-hydroxytricyclo<3.3.1.1^3,7>decane 
• 281-23-2 adamantane 
• 768-90-1 1-Adamantyl bromide 
• 58652-54-3 1-adamantyl trifluoroacetate 
• 935-56-8 1-chloroadamantane 
• 32314-61-7 1-nitroxyadamantane 
• 700-57-2 1-adamantanol 
• 768-95-6 1-adamanthanol 

Downstream Products

• 97745-35-2 1-adamantyl-O,O-diphenylphosphonate 
• 60509-83-3 (adamantan-1-yl)diphenylphosphine oxide 

Relevant articles and documents

Optimised synthesis and characterisation of 1-adamantyltrimethylphosphonium iodide

A synthetic route to multigram quantities of 1-adamantyltrimethylphosphonium iodide is reported. The synthesis starts from the commercially available precursor 1-adamantyl bromide and was optimised with respect to yield and ease of purification. The title compound is of interest to zeolite chemists as a potent organic structure-directing agent. Full spectroscopic characterisation data of all isolated intermediates and single crystal X-ray diffraction data of AdP(O)Cl2, [AdPMe2H]I and [AdPMe3]I (Ad?=?1-adamantyl) are reported.

AlCl3-catalyzed dichlorophosphorylation of saturated hydrocarbons with PCl3 in methylene chloride solution

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Defying Stereotypes with Nanodiamonds: Stable Primary Diamondoid Phosphines

Direct unequal C-H bond difunctionalization of phosphorylated diamantane was achieved in high yield from the corresponding phosphonates. Reduction of the functionalized phosphonates provides access to novel primary and secondary alkyl/aryl diamantane phos

Phosphorylation of Adamantane and its Derivatives in Trifluoroacetic Acid Medium

The possibility of dichlorophosphorylation of the carcass compounds of the adamantane series and of aryl(alkyl)carbinols, with phosphorus trichloride in the low-nucleophilicity trifluoroacetic acid medium was first demonstrated. A new preparative method for introducing a POCl2 group into the bridgehead and bridge positions of the adamantane nucleus, as well as into the α position of the side chain was developed. Some intermediate adamantyl cations may undergo isometizations, among them skeleton ones. A mechanism of the phosphorylation was proposed.