239090-00-7Relevant academic research and scientific papers
Synthesis of new enantiomerically pure monoketals of p-benzoquinone with C2-symmetry
De March, Pedro,Figueredo, Marta,Font, Josep,Medrano, Jordi
, p. 7907 - 7914 (1999)
Several new monoketals of p-benzoquinone with the structure of 1,3- dioxaspiro[4.5]deca-6,9-dien-8-one have been synthesised in enantiopure form by the straightforward reaction of the quinone with secondary C2-symmetric 1,2-diols. The preparati
The attempted stereoselective synthesis of chiral 2,2′-biindoline
Gresser, Mary J.,Wales, Steven M.,Keller, Paul A.
experimental part, p. 6965 - 6976 (2010/09/18)
The attempted first stereoselective synthesis of 2,2′-biindoline using a metathesis-Sharpless asymmetric dihydroxylation strategy results in the synthesis of the heterocycle in poor to modest stereoselectivity. Attempts to improve the ee by varying the he
