239092-65-0

Basic information

• Product Name: 4-Ethoxy-5-methyl-5-(4-phenoxyphenyl)-3-oxazolin-2-on
• Synonyms: 4-Ethoxy-5-methyl-5-(4-phenoxyphenyl)-3-oxazolin-2-on
• CAS NO: 239092-65-0
• Molecular Weight: 311.337
• Mol File: 239092-65-0.mol

Chemical Properties

• CAS DataBase Reference: 4-Ethoxy-5-methyl-5-(4-phenoxyphenyl)-3-oxazolin-2-on(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Ethoxy-5-methyl-5-(4-phenoxyphenyl)-3-oxazolin-2-on(239092-65-0)
• EPA Substance Registry System: 4-Ethoxy-5-methyl-5-(4-phenoxyphenyl)-3-oxazolin-2-on(239092-65-0)

Safety Data

• Hazardous Substances Data: 239092-65-0(Hazardous Substances Data)

Upstream product

• 530-62-1 1,1'-carbonyldiimidazole 

Relevant articles and documents

Synthesis, properties and fungicidal activity of 4-hydroxy(alkoxy)imino-oxazolidin-2-ones

4-Hydroxyimino-oxazolodin-2-ones (3) were prepared by hydroxylaminolysis of 4-alkoxy-3-oxazolin-2-ones (2). Treatment of 3a with ethyl chloroformate in a molar ratio of 1:1 afforded 6, whereas the reaction 3a with two equivalents of ethyl chloroformate produced 4 and 5. By reacting 3a,d with diphosgene or thiophosgene the novel tetrahydro-oxazolo [4,3-c]1,2,4-oxadiazoles 7 could be obtained in low yields. From the prepared novel compounds only 3a displayed a remarkable fungicidal activity at 2 ppm.

Synthesis and fungicidal activity of 4-arylhydrazono-oxazolidin-2-ones

Cyclic carbonylation of the glycoloimidates 1 with 1,1'- carbonyldiimidazole (CDI) gives 4-ethoxy-3-oxazolin-2-ones (3), the arylhydrazinolysis of which affords 4-arylhydrazono-oxazolidin-2-ones (5). Although the novel compounds 5b-f displayed remarkable fungicidal activity in-vitro against selected phytopathogenic fungi, no significant activity could be established in the greenhouse.