239802-99-4

Upstream product

• 64650-81-3 allyl α-L-rhamnopyranoside 
• 1125-88-8 benzaldehyde dimethyl acetal 

Downstream Products

• 1219934-86-7 C₂₄H₂₈O₆ 
• 1253793-27-9 allyl 2,3-O-benzylidene-4-O-benzyl-α-L-rhamnopyranoside 
• 138824-96-1 Acetic acid (2S,3S,4R,5R,6S)-6-[(2S,3S,4R,5R,6S)-6-((2S,3S,4R,5R,6R)-6-allyloxy-4,5-bis-benzyloxy-2-methyl-tetrahydro-pyran-3-yloxy)-4,5-bis-benzyloxy-2-methyl-tetrahydro-pyran-3-yloxy]-4,5-bis-benzyloxy-2-methyl-tetrahydro-pyran-3-yl ester 
• 127085-21-6 (2S,3S,4R,5R,6S)-6-[(2S,3S,4R,5R,6S)-6-((2S,3S,4R,5R,6R)-6-Allyloxy-4,5-bis-benzyloxy-2-methyl-tetrahydro-pyran-3-yloxy)-4,5-bis-benzyloxy-2-methyl-tetrahydro-pyran-3-yloxy]-4,5-bis-benzyloxy-2-methyl-tetrahydro-pyran-3-ol 
• 138824-97-2 Acetic acid (2S,3S,4R,5R,6S)-4,5-bis-benzyloxy-6-[(2S,3S,4R,5R,6S)-4,5-bis-benzyloxy-6-((2S,3S,4R,5R,6S)-4,5-bis-benzyloxy-6-chloro-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-2-methyl-tetrahydro-pyran-3-yl ester 
• 138824-95-0 Acetic acid (2S,3S,4R,5R,6S)-6-((2S,3S,4R,5R,6R)-6-allyloxy-4,5-bis-benzyloxy-2-methyl-tetrahydro-pyran-3-yloxy)-4,5-bis-benzyloxy-2-methyl-tetrahydro-pyran-3-yl ester 
• 127085-19-2 (2S,3S,4R,5R,6S)-6-((2S,3S,4R,5R,6R)-6-Allyloxy-4,5-bis-benzyloxy-2-methyl-tetrahydro-pyran-3-yloxy)-4,5-bis-benzyloxy-2-methyl-tetrahydro-pyran-3-ol 
• 127102-20-9 allyl 2,3-O-benzyl-4-O-tertbutyldimethylsilyl-α-L-rhamnopyranoside 
• 138825-05-5 2,3-O-benzyl-4-O-acetyl-α-L-rhamnopyranoside 
• 138825-06-6 Acetic acid (2S,3S,4R,5R,6R)-4,5-bis-benzyloxy-2-methyl-6-[((E)-propenyl)oxy]-tetrahydro-pyran-3-yl ester 
• 138824-94-9 Acetic acid (2S,3S,4R,5R,6S)-4,5-bis-benzyloxy-6-chloro-2-methyl-tetrahydro-pyran-3-yl ester 
• 127875-17-6 Acetic acid (2S,3S,4R,5R,6R)-4,5-bis-benzyloxy-6-hydroxy-2-methyl-tetrahydro-pyran-3-yl ester 
• 127085-16-9 allyl 2,3-di-O-benzyl-α-L-rhamnopyranoside 
• 239803-00-0 ((3aR,4R,6S,7S,7aS)-4-Allyloxy-6-methyl-2-phenyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yloxy)-tert-butyl-diphenyl-silane 

Relevant academic research and scientific papers

Facile glycosylation strategy with two-stage activation of allyl glycosyl donors. Application to concise synthesis of Shigella flexneri serotype y O-antigen

A practical, useful glycosylation method employing only allyl glycoside building blocks has been developed. The donor's glycosylation reactivity is turned on via isomerization of its anomeric allyl protecting group into the corresponding prop-1-enyl moiet

TOTAL SYNTHESIS OF CYCLO-L-RHAMNOHEXAOSE BY A STEREOSELECTIVE THERMAL GLYCOSYLATION

The first cyclooligosaccharide of L series, cyclo-L-rhamnohexaose, have been synthesized from L-rhamnose by α-selective thermal glycosylation and PhSeOTf promoted cycloglycosylation.