23993-49-9

Basic information

• Product Name: Acetamide, N-((4-methoxyphenyl)methoxy)-
• Synonyms: Acetamide, N-((4-methoxyphenyl)methoxy)-
• CAS NO: 23993-49-9
• Molecular Formula: C₁₀H₁₃NO₃
• Molecular Weight: 195.2151
• Mol File: 23993-49-9.mol
• Article Data: 1

Chemical Properties

• Melting Point: 88-89 °C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: 1.115g/cm³
• Refractive Index: 1.511
• CAS DataBase Reference: Acetamide, N-((4-methoxyphenyl)methoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetamide, N-((4-methoxyphenyl)methoxy)-(23993-49-9)
• EPA Substance Registry System: Acetamide, N-((4-methoxyphenyl)methoxy)-(23993-49-9)

Safety Data

• Hazardous Substances Data: 23993-49-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H13NO3/c1-8(12)11-14-7-9-3-5-10(13-2)6-4-9/h3-6H,7H2,1-2H3,(H,11,12)

Upstream product

• 546-88-3 acetylhydroxamic acid 
• 824-94-2 p-methoxybenzyl chloride 

Downstream Products

• 53821-07-1 N,N'-diacetyl-N,N'-di-(p-methoxybenzyloxy)hydrazine 

Relevant articles and documents

HERON rearrangement of N,N'-diacyl-N,N'-dialkoxyhydrazines a - Theoretical and experimental study

Ab initio calculations at the B3LYP/6-31G* level on N-methoxy-N- dimethylaminoformamide and its rearrangement to methyl formate and 1,1- dimethyldiazene through the HERON reaction, have been carded out in conjunction with an experimental study of the HERON reactions of N,N'- diacyl-N,N'-dialkoxyhydrazines. Substituent effects are in accord with the theoretical properties of the transition state and point to an anomerically driven process in which donor groups on the anomeric nitrogen and withdrawing groups on the migrating alkoxy oxygen facilitate the rearrangement process.