240116-09-0Relevant articles and documents
Synthesis of the enantiopure C15-C26 segment of phorboxazole A and B
Wolbers, Peter,Misske, Andrea M.,Hoffmann, H. Martin R.
, p. 4527 - 4530 (1999)
Two approaches towards an enantiopure C15-C26 segment of the phorboxazoles starting from the corresponding C20-C26 aldehyde are presented. A variety of functionalized oxazoles have been synthesized via the rhodium(II) acetate catalyzed cycloaddition of dimethyl diazomalonate to substituted nitriles.