240120-05-2

Upstream product

• 240119-96-4 4-<2-(trifluoromethylsulfonyloxy)cyclohex-1-enyl>-(1,2S)-butanediol, O-3-pentylidene acetal 
• 240119-94-2 4-<2-(trimethylsilanyloxy)cyclohex-1-enyl>-(1,2S)-butanediol, O-3-pentylidene acetal 
• 240119-92-0 (2RS)-<<(3S,4)-O-3-pentylidene-3,4-dihydroxybutan>-1-yl>cyclohexanone 
• 2108-60-3 trimethyl{(E)oct-1-enyl}stannane 
• 10424-93-8 N'-cyclohexylidene-N,N-dimethyl-hydrazine 
• 240120-00-7 1-<<1-(3S,4)-dihydroxybutyl>cyclohex-1-enyl>non-2-en-1-one, O-3-pentylidene acetal 

Downstream Products

• 240119-80-6 1-<2-<(3R)-azido-4-tert-butyldimethylsilyloxybutyl>cyclohex-1-enyl>non-2-en-1-one 
• 240120-14-3 1-<2-<(3S)-methanesulfonyloxy-4-tert-butyldimethylsilyloxybutyl>cyclohex-1-enyl>non-2-en-1-one 
• 240120-10-9 1-<2-<(3S)-hydroxy-4-tert-butyldimethylsilyloxybutyl>cyclohex-1-enyl>non-2-en-1-one 

Relevant academic research and scientific papers

Total Synthesis of (-)-Cylindricine C

(-)-Cylindricine C has been synthesized from commercially available (S)-(-)-1,2,4-butanetriol in 11 steps with an overall yield of 12%. The key step utilizes a CrCl2 reduction of an azide to form the corresponding amine with a subsequent double Michael addition to create the tricyclic skeleton of cylindricine from a monocyclic substrate.