240415-68-3Relevant academic research and scientific papers
Claisen-Ireland rearrangement: A new route to C-glycosides
Vidal, Thierry,Haudrechy, Arnaud,Langlois, Yves
, p. 5677 - 5680 (1999)
A Claisen-Ireland rearrangement led to the formation of C-glycan derivatives. Azidonitration-reduction or dihydroxylation afforded gluco- and galacto-derived β-C-glycosides. Subsequent deprotonation of bicyclic lactones 16 allowed the control of the newly created asymmetric centre.
