2408-04-0Relevant academic research and scientific papers
Copper-catalyzed direct trifluoromethylthiolation of benzylic C-H bonds via nondirected oxidative C(sp3)-H activation
Chen, Chao,Xu, Xiu-Hua,Yang, Bin,Qing, Feng-Ling
supporting information, p. 3372 - 3375 (2014/07/08)
A copper-catalyzed trifluoromethylthiolation of benzylic sp3 C-H bonds was developed via nondirected oxidative C-H activation using readily prepared and stable AgSCF3. This reaction provides a novel and straightforward method for the preparation of various benzyl trifluoromethyl sulfides.
Gas-phase acidities of α- and α,α-SO2CF 3-substituted toluenes. Varying Resonance demand in the electron-rich system
Zhang, Min,Badal, Md. Mizanur Rahman,Koppel, Ilmar A.,Mishima, Masaaki
, p. 813 - 820 (2013/08/15)
The gas-phase acidities (GA) of aryl(trifluoromethylsulfonyl)methanes (ArCH2SO2CF3; 1) and arylbis(trifluoromethylsulfonyl) methanes (ArCH(SO2CF 3)2; 2) were determined by measuring proton-
