240809-13-6

Basic information

• Product Name: (C₅H₅)Fe(C₅H₄C₃H(CH₂C₆H₅)NO₂)PtCl₂(P(CH₂CH₃)3)
• CAS NO: 240809-13-6
• Molecular Weight: 743.352
• Mol File: 240809-13-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₅H₅)Fe(C₅H₄C₃H(CH₂C₆H₅)NO₂)PtCl₂(P(CH₂CH₃)3)(CAS DataBase Reference)
• NIST Chemistry Reference: (C₅H₅)Fe(C₅H₄C₃H(CH₂C₆H₅)NO₂)PtCl₂(P(CH₂CH₃)3)(240809-13-6)
• EPA Substance Registry System: (C₅H₅)Fe(C₅H₄C₃H(CH₂C₆H₅)NO₂)PtCl₂(P(CH₂CH₃)3)(240809-13-6)

Safety Data

• Hazardous Substances Data: 240809-13-6(Hazardous Substances Data)

Upstream product

• 240809-01-2 (C₅H₅)Fe(C₅H₄C₃H(CH₂C₆H₅)NO₂) 
• 15282-39-0 [Pt2Cl2(μ-Cl)2(PBu3)2] 

Relevant articles and documents

Metal complexes of biologically important ligands, CXIV ferrocenyl-oxazolones as N and C donors in Pd(II), Pt(II) and Ir(III) complexes and ferrocenoyl-dipeptides

2-Ferrocenyl-4R-5(4H)-oxazolones 1-5 were obtained from N-ferrocenoyl-α-amino acids and function as N donors in dichloro-phosphine-palladium(II) and platinum(II) complexes 6-18. The reaction of ferrocenyl-oxazolone and ferrocenyl-bis(oxazolone) with [Cp*IrCl2]2 afforded trimetallic and pentametallic complexes 19 and 20 with a C,N bridging oxazolone. Ring opening of the ferrocenyl-oxazolones 1, 2 and 4 with α-amino acid esters gave N-ferrocenoyl-dipeptide esters 21-26. In the ferrocene bis(dipeptides) the two peptide esters are aligned parallel by hydrogen bonding. The structures of 6 and 19 were determined by X-ray diffraction.