24084-15-9

Upstream product

• 1103533-46-5 S-2-bromophenethyl ethanethioate 

Downstream Products

• 1025921-35-0 4-Hydroxy-4-[2-(2-mercapto-ethyl)-phenyl]-piperidine-1-carboxylic acid ethyl ester 
• 697745-48-5 allyl 4-acetoxy-4-benzyl-3-[2-(2-bromophenyl)ethylsulfanyl]-5-phenylpentanoate 
• 934538-82-6 thiophosphoric acid S-[2-(2-bromo-phenyl)-ethyl] ester O,O'-diethyl ester 
• 934538-81-5 diphenyl-phosphinothioic acid S-[2-(2-bromo-phenyl)-ethyl] ester 
• 934538-83-7 2-[2-(2-bromo-phenyl)-ethylsulfanyl]-1,3-dimethyl-[1,3,2]diazaphospholidine 2-oxide 

Relevant academic research and scientific papers

Intramolecular homolytic substitution at the sulfur atom: an alternative way to generate phosphorus- and sulfur-centered radicals

Two efficient procedures involving tin hydride or thiophenol-mediated intramolecular homolytic substitution at the sulfur atom are reported. They lead to the generation of varied P(V)-centered radicals from the corresponding aryl or alkyne thiophosphorus substrates. The radical formed can be trapped by an olefin via an intermolecular addition, leading to the construction of C-P bonds. Thiophosphination of triple bonds was also achieved using a radical cycloisomerization process. Extension of the methodology to sulfur-containing species was examined.