24085-65-2

Basic information

• Product Name: Ether,bis(p-tert-butylphen
• Synonyms: Ether,bis(p-tert-butylphen;Bis(4-tert-butylphenyl) ether;Bis(p-tert-butylphenyl) ether
• CAS NO: 24085-65-2
• Molecular Formula: C₂₀H₂₆O
• Molecular Weight: 282.42
• Mol File: 24085-65-2.mol
• Article Data: 11

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ether,bis(p-tert-butylphen(CAS DataBase Reference)
• NIST Chemistry Reference: Ether,bis(p-tert-butylphen(24085-65-2)
• EPA Substance Registry System: Ether,bis(p-tert-butylphen(24085-65-2)

Safety Data

• Hazardous Substances Data: 24085-65-2(Hazardous Substances Data)

Upstream product

• 123324-71-0 p-tert-butylphenylboronic acid 
• 31166-44-6 phenylmethyl 1-piperazinecarboxylate 
• 3972-65-4 1-bromo-4-tert-butylbenzene 
• 98-54-4 para-tert-butylphenol 
• 253185-03-4 tert-butylbenzene 
• 50-00-0 formaldehyd 
• 35779-04-5 1-tert-butyl-4-iodobenzene 

Downstream Products

• 253185-03-4 tert-butylbenzene 
• 98-54-4 para-tert-butylphenol 
• 90-47-1 xanth-9-one 
• 92-83-1 xanthene 

Relevant articles and documents

Catalytic conversion of 4-tert-butylphenol in hydrogen peroxide solutions in the presence of titanium oxide compounds and titanosilicates

The catalytic conversion of 4-tert-butylphenol (TBP) in hydrogen peroxide solutions in the presence of titanium oxide samples with different phase compositions and crystalline and amorphous titanosilicate samples has been studied. It has been shown that microporous crystalline titanosilicate TS-1 exhibits low activity in the TBP conversion owing to steric restrictions to the diffusion of the substrate molecules to catalytically active sites. The samples of titanium oxide compounds and mesoporous titanosilicates exhibit similar activity, while the selectivity of the latter for 4-tert-butylcatechol (TBC) is higher. The effect of the mesoporous titanosilicate concentration in the reaction mixture and the test temperature and duration on the TBP conversion and the TBC selectivity has been determined.

Synthesis and Characterization of Acridinium Dyes for Photoredox Catalysis

Photoredox catalysis is a rapidly evolving platform for synthetic methods development. The prominent use of acridinium salts as a sustainable option for photoredox catalysts has driven the development of more robust and synthetically useful versions based on this scaffold. However, more complicated syntheses, increased cost, and limited commercial availability have hindered the adoption of these catalysts by the greater synthetic community. By utilizing the direct conversion of a xanthylium salt into the corresponding acridinium as the key transformation, we present an efficient and scalable preparation of the most synthetically useful acridinium reported to date. This divergent strategy also enabled the preparation of a suite of novel acridinium dyes, allowing for a systematic investigation of substitution effects on their photophysical properties.

Reductive Cleavage of C—O Bond in Model Compounds of Lignin

A simple protocol for reductive cleavage of C—O bond in diaryl and aryl methyl ethers was reported, in which NaH served as a reducing agent and KOtBu as a base and a radical initiator. The combination of NaH and KOtBu displayed high efficiency for reductive cleavage of C—O bond in diaryl and aryl ethers (e.g., dibenzofuran, diphenyl ether, anisole) without the hydrogenation of the aryl rings, in the absence of any other catalysts or ligands at 140 °C, producing corresponding arenes and phenols. It was indicated that the reaction was under a radical mechanism.