241-28-1

Upstream product

• 37846-72-3 (1-naphthylmethyl)magnesium chloride 
• 78018-48-1 2--2,3-dihydro-1H-indan-1-one 
• 134576-20-8 7-(Methylthio)-8H-indeno<2,1-b>phenanthrene 
• 13974-81-7 2-styrylfluorene 

Relevant academic research and scientific papers

Cycloaromatization of α-oxoketene dithioacetals and β-oxodithioacetals with benzyl-,1-(naphthylmethyl) and 2-(naphthylmethyl)magnesium halides: Synthesis of condensed polynuclear aromatic hydrocarbons

An efficient route for the synthesis of substituted naphthalenes, phenanthrenes and other polynuclear aromatic hydrocarbons has been developed. The methodology involves 1,2- (or sequential 1,4- and 1,2-) addition of either benzyl, 1-(naphthylmethyl) or 2-(naphthylmethyl) magnesium halides to α-oxoketene dithioacetals or β-oxodithioacetals followed by borontrifluoride etherate catalyzed cycloaromatization of the resulting carbinols.

Synthesis of Oxygenated Metabolites of Indenopyrene

The syntheses of cis- and trans-1,2-dihydro-1,2-dihydroxyindenopyrene, 1,2-dihydroindenopyrene 1,2-epoxide, and 1-, 2-, 6-, 7-, 8-, 9-, and 10-hydroxyindenopyrene are described.UV and high-resolution NMR spectral data are rep