24120-79-4

Basic information

• Product Name: (1R,2R,4S,6S)-(-)-1-methyl-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]heptan-2-ol
• Synonyms: (1R,2R,4S,6S)-(-)-1-methyl-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]heptan-2-ol
• CAS NO: 24120-79-4
• Molecular Weight: 168.236
• Mol File: 24120-79-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (1R,2R,4S,6S)-(-)-1-methyl-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]heptan-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2R,4S,6S)-(-)-1-methyl-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]heptan-2-ol(24120-79-4)
• EPA Substance Registry System: (1R,2R,4S,6S)-(-)-1-methyl-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]heptan-2-ol(24120-79-4)

Safety Data

• Hazardous Substances Data: 24120-79-4(Hazardous Substances Data)

Upstream product

• 36616-60-1 (1R,4R,6R)-4-isopropenyl-1-methyl-7-oxabicyclo[4.1.0]heptan-2-one 
• 99-48-9 (4R,6R)-carveol 
• 6485-40-1 (R)-Carvone 

Downstream Products

• 191410-13-6 1-((1R,3S,5R,6S)-5-Hydroxy-6-methyl-7-oxa-bicyclo[4.1.0]hept-3-yl)-ethanone 
• 1154606-95-7 tert-butyl{[(1R,2R,4R,6R)-4-isopropenyl-1-methyl-7-oxabicyclo[4.1.0]hept-2-yl]oxy}diphenylsilane 
• 182700-04-5 (1R,2R,4R)-(-)-(2-hydroxy-4-(prop-1-en-2-yl)cyclopentyl)ethan-1-one 
• 1259529-38-8 (1S,2S,4R,6S)-1-methyl-4-(prop-1-en-2-yl)-7-oxabicyclo[4.1.0]heptan-2-yl 4-nitrobenzoate 
• 1259529-39-9 (1S,2S,4R,6S)-4-acetoxy-1-methyl-7-oxabicyclo[4.1.0]heptan-2-yl 4-nitrobenzoate 
• 7632-16-8 (2S,4S)-carveol 
• 99624-67-6 7R-Paeonimetabolin-I 
• 99624-67-6 7S-Paeonimetabolin-I 

Relevant articles and documents

VITAMIN D RECEPTOR ACTIVATORS AND METHODS OF MAKING

The invention relates to compounds that are vitamin D receptor activators, compositions comprising such compounds, methods of using such compounds and compositions, processes for preparing such compounds, and intermediates obtained during such processes.

(R)-Carvone as chiral template for the synthesis of some polyols

Some (4S,6R,7R) 4,6,7-trihydroxyheptyl derived building blocks have been obtained from (R)-carvone as the chiral template.A key-step is the Baeyer-Villiger oxidation of a suitable intermediate.

Efficient Enantiospecific Synthesis of Key A-Ring Synthons for the Preparation of 1α,25-Dihydroxyvitamin D3 Using a Chromium((II)-Mediated Reaction

Key A-ring synthons for the synthesis of 1α,25-dihydroxyvitamin D3 have been prepared efficiently from (R)-(-)-carvone by use of diastereoselective chromium(II)-mediated addition of an allylic halide to an aldehyde as a key step.