24153-13-7Relevant articles and documents
Site-selective c-h acylation of pyridinium derivatives by photoredox catalysis
Jung, Sungwoo,Lee, Hyeonyeong,Moon, Yonghoon,Jung, Hoi-Yun,Hong, Sungwoo
, p. 9891 - 9896 (2019/10/14)
A strategy for visible-light-induced site-selective C-H acylation of pyridinium salts was developed by employing N-methoxy-or N-aminopyridinium salts, offering a powerful synthetic tool for accessing highly valuable C2- A nd C4-acylated pyridines. The met
Cobalt-Catalyzed α-Alkylation of Ketones with Primary Alcohols
Zhang, Guoqi,Wu, Jing,Zeng, Haisu,Zhang, Shu,Yin, Zhiwei,Zheng, Shengping
supporting information, p. 1080 - 1083 (2017/03/14)
An ionic cobalt-PNP complex is developed for the efficient α-alkylation of ketones with primary alcohols for the first time. A broad range of ketone and alcohol substrates were employed, leading to the isolation of alkylated ketones with yields up to 98%. The method was successfully applied to the greener synthesis of quinoline derivatives while using 2-aminobenzyl alcohol as an alkylating reagent.
Intramolecular cation-π interactions control the conformation of nonrestricted (phenylalkyl)pyridines
Richter, Isabella,Minari, Jusaku,Axe, Philip,Lowe, John P.,James, Tony D.,Sakurai, Kazuo,Bull, Steven D.,Fossey, John S.
, p. 1082 - 1084 (2008/12/20)
NOEsy and fluorescence spectroscopy reveal that conversion of conformationally flexible (phenylalkyl)pyridines into their corresponding N-methyl-pyridinium iodides results in intramolecular π-stacking. The Royal Society of Chemistry.
