24155-50-8Relevant academic research and scientific papers
Metal-free, n-Bu4NI-catalyzed regioselective difunctionalization of unactivated alkenes
Xue, Qicai,Xie, Jin,Xu, Pan,Hu, Kaidong,Cheng, Yixiang,Zhu, Chengjian
, p. 1365 - 1368 (2013/07/26)
A new synthetic approach toward difunctionalization of alkenes has been developed under metal-free conditions. Various carboxylic acids and amines could react smoothly with alkenes to give dioxygenation and oxyamidation products, respectively. This organocatalytic process delivers 2-hydroxy alcohols directly from simple alkenes with high levels of region control.
Copper-catalyzed C-H alkoxylation of azoles
Takemura, Noriaki,Kuninobu, Yoichiro,Kanai, Motomu
supporting information, p. 844 - 847 (2013/03/28)
We achieved copper-catalyzed intramolecular and intermolecular alkoxylation of azoles. This reaction is a rare example of transition-metal-catalyzed C-H alkoxylation of heteroaromatic compounds. In addition, the alkoxylation reaction proceeded well even i
